research project will be the synthesis
and stabilization of high-valent early
first-row transition metal complexes by
encapsulation in zeolite cages. While
initial studies will focus on terminal
oxo and nitrido complexes, the investigation
of a variety of chalcogenido and pnictogenido
compounds of V, Cr, Mn and Fe is envisioned.
Major goals of this project include in
situ spectroscopic characterization of
reactive species and exploration of their
Hu & Karsten Meyer
Identification of Iron Cyclam Complexes
Encapsulated Inside Zeolite Y. Inorg.
Chim. Acta. 2002, 337,